I wish the ACC would arrange the schedule so PITT plays Da 'U' as the Final Game each Season, as that could build a long term New Rival. Also, when the Games are are at PITT in late November(would prefer the Friday after Thanksgiving unless the Season would end in December), the chance of Cold Temps and once in awhile possible snow, would provide a Nice Home Field Advantage. Although for Games in Miami, the Warmer Temps that time of year might have PITT Players feeling like it is a Pleasure Trip and maybe not as focused on the Game, as they should be, but that is up to the Coaches to establish the Culture of playing well in those Games.
Also, if PITT does not play in a Bowl Game or in one at a terrible location, Road Trip to Away Games in Miami is more appealing in late November or early December(and most Players headed to the NFL Draft are wise to skip meaningless Bowl Games anyways, and really, if not in the Playoffs, then not worth risking an injury by playing in any other Bowl Game(including the StepDaddy of them all-The Rose Bowl on years that place is not in the Playoffs Rotation Schedule).
Actually, if Notre Dame ever joins the ACC(doubt that will ever happen though once the Playoffs eventually expand to 8 Teams that provides ND even more of a chance to make the Playoffs), then I would love for Notre Dame to play PITT at the end of the year, but think their Final Game is usually at USC or Stanford, although if they join the ACC, not sure if they would be able to play Stanford every year, but assume the USC and Navy Games are 2 Schools that ND would always play on their OOC Schedule, if they ever did join the ACC(although again, doubt it will happen, since they did not like being a Full Time ACC Member enough this past year to consider joining permanently).
I could only see ND considering joining the ACC as a Full Time Member though, if Navy would be the 16th School added to help with ND keeping them on their Schedule without using one of their OCC Games for Navy. Then again, seeing some of the Schools ND is playing next year, hard to understand how they ended a long time scheduled game with Michigan State(think is the School who played ND the 3rd most Games after USC and Navy, then PITT maybe 4th or 5th as the most Games as an opponent for ND, but maybe someone else here can verify it, as I am not absolutely sure).
If WVU ever does get invited to join the ACC, then of course that Game already being a Rivalry, would be the best option as the Final Game each year. No idea though how many more years until Conferences can raid other Conference Teams again, and even if it happens, if the ACC would want to get WVU(Academics Reputation is no longer an excuse not to consider adding WVU, since the ACC invited Louisville, and if ND will not join, then the ACC would be best to also add Central Florida, as that School has a Large Student Population, and has developed a Strong Program with a Few Coaches over the past Decade, so if they hire another Good AD and HC, no reason for them to at least not remain competitive, especially with the Recruiting Area of the Entire State, that joining the ACC will only help UCF get some of the Better Florida Recruits, or at least the Better 3 Star Recruits).
Sorry, but playing Syracuse the end of the Season, despite the longer number of years of PITT having played them, just is not that exciting to me, but YMMV.